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MDGeist said:
youre doing it wrong, the only thing photoshop can vector are simple lines/strokes. As soon as you fill some color you´ll have a bitmap graphic which will look like shit when enlarged/shrinkd/reenlarged
well, that's what i do, lines. then i go "stroke paths" and there, i got the lineart, working at high resolution so it won't need to be enlarged. then i paint the picture...

if that's not the correct way of vectoring, it's ok. i'm not too into it.