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MDGeist said:
youre doing it wrong, the only thing photoshop can vector are simple lines/strokes. As soon as you fill some color you´ll have a bitmap graphic which will look like shit when enlarged/shrinkd/reenlarged
If you use shape layers (as opposed to paths), you don't need to fill/stroke anything and they can be upscaled without losing information. It's perfectly possible to vector in Photoshop.