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Velen said:
If you use shape layers (as opposed to paths), you don't need to fill/stroke anything and they can be upscaled without losing information. It's perfectly possible to vector in Photoshop.
and how to export it to svg or similar ?
edit : just tested, lol no you cant! i see pixels everywhere
PS IS NOT VECTOR, ITS PIXEL BASED! Once color = game over!

photoshop vectors are all a fixed resolution, as you can only export paths to illus.
if you only do paths to begin with, why not use illustrator to begin with? its way better to use illustrator for vectorting as it is adobes program for vectors, ps vec support is only for basic stuff.

ps is good for making wallpapers of anime screenshots and shit, but not to vector a scan/screenshot to make it "pillow printable"!